Method for the simultaneous determination of residues of chemotherapeutic agents, antiparasitic agents and growth promoters in food of animal origin. 3. Determination of chloramphenicol and meticlorpindol

Chloramphenicol and meticlorpindol may be determined by HPLC with UV-detection with a limit of 0.02-0.03 mg/kg. Residues of 0.001 mg/kg Chloramphenicol are determined by Capillary-GC with an ECD after an additional clean up step using chromatography on a miniaturized silica column, followed by a silylation step. HMDS/TMCS/Pyridine forms the disilylated Chloramphenicol. In samples of eggs, milk and meat the limit of detection is roughly 0.0002 mg/kg and is adequate to check the FDR tolerance levels for these foods. The proposed method was checked with residues of chloramphenicol in the range of 0.0005 to 0.005 mg/kg in milk from animals dosed with chloramphenicol. Results obtained by this method and results of a RIA-method correlated very well. The analytical procedure (applicable for all substances) was abbreviated compared to the method reported in the first communication on this topic.     

Study of possibilities for a spin flip in high energy electron ring HERA

In a high energy electron ring the spins of electrons become spontaneously polarized via the emission of spin-flip synchrotron radiation. By employing a radio frequency radial dipole field kicker, particle spin directions can be rotated slowly over many turns. A model which couples three dimensional spin motion and longitudinal particle motion was constructed to describe nonequilibrium spin dynamics in high energy electron storage rings. The effects of a stochastic synchrotron radiation on the orbital motion in the accelerator synchrotron plane and its influence on the spin motion are studied. The main contributions to the spin motion, the synchrotron oscillations and the stochastic synchrotron radiation, have different influence on the spin polarization reversal in different regions of the parameter space. The results indicate that polarization reversal might be obtained in high energy electron storage rings with a significant noise even with relatively small strengths of a perturbing magnetic field. The only experimental datum available agrees with the model prediction, however further experimental data would be necessary to validate the model.     

A method to study the history of a double oxide film defect in liquid aluminum alloys

Entrained double oxide films have been held responsible for reductions in mechanical properties in aluminum casting alloys. However, their behavior in the liquid metal, once formed, has not been studied directly. It has been proposed that the atmosphere entrapped in the double oxide film defect will continue to react with the liquid metal surrounding it, perhaps leading to its elimination as a significant defect. A silicon-nitride rod with a hole in one end was plunged into liquid aluminum to hold a known volume of air in contact with the liquid metal at a constant temperature. The change in the air volume with time was recorded by real-time X-ray radiography to determine the reaction rates of the trapped atmosphere with the liquid aluminum, creating a model for the behavior of an entrained double oxide film defect. The results from this experiment showed that first oxygen, and then nitrogen, was consumed by the aluminum alloy, to form aluminum oxide and aluminum nitride, respectively. The effect of adding different elements to the liquid aluminum and the effect of different hydrogen contents were also studied. This article is based on a presentation made in the John Campbell Symposium on Shape Casting, held during the TMS Annual Meeting, February 13–17, 2005, in San Francisco, CA.     

A Platform-Based Taxonomy for ESL Design

This article presents a taxonomy for ESL tools and methodologies that combines UC Berkeley's platform-based design terminologies with Dan Gajski's Y-chart work. This is timely and necessary because in the ESL world we seem to be building tools without first establishing an appropriate design flow or methodology, thereby creating a lot of confusion. This taxonomy can help stem the tide of confusion.     

The effects of deep zones on wetland nitrogen processing.

Twelve research wetlands were operated under varying conditions at a site west of the city of Phoenix. These were constructed as a triplicated design, with zero, one, two and three internal deep zones, all containing an inlet distribution and an outlet collection deep zone, together comprising 12.5-35% of the wetland areas. The water supply was partially nitrified effluent from a city wastewater treatment plant. Total nitrogen was reduced by about 50%, from inflow concentrations between 6 and 8 mg/L. Speciation of the inflow was approximately 25% organic nitrogen, 25% ammonium nitrogen and 50% nitrate nitrogen. Typical outflow concentrations were about 1.2 mg/L organic, 0.5 mg/L ammonium and 0.0-2.5 mg/L nitrate. Rate constants for total nitrogen were 15-20 m/year at 20 degrees C, and 20-30 m/year for nitrate, which agree well with other project reports. Temperature factors averaged 1.100 for total nitrogen, and 1.184 for nitrate. There were no differences in the internal hydraulics with deep zone numbers. Deep zone numbers in the wetlands did not affect nitrogen treatment performance. No differences with deep zone numbers were found for temperature, dissolved oxygen, pH, or nitrogen removals or rate constants. In conjunction with other reported results, there appears to be no large treatment benefit or detriment of incorporating internal deep zones in free water surface wetlands.     

Public grid computing participation: An exploratory study of determinants

Using the Internet, “public” computing grids can be assembled using “volunteered” PCs. To achieve this, volunteers download and install a software application capable of sensing periods of low local processor activity. During such times, this program on the local PC downloads and processes a subset of the project's data. At the completion of processing, the results are uploaded to the project and the cycle repeats.     

A systematic approach for product families formation in Reconfigurable Manufacturing Systems

The aim of this work is to establish a methodology for an effective working of Reconfigurable Manufacturing Systems (RMSs). These systems are the next step in manufacturing, allowing the production of any quantity of highly customised and complex products together with the benefits of mass production. In RMSs, products are grouped into families, each of which requires a system configuration. The system is configured to produce the first family of products. Once it is finished, the system is reconfigured in order to produce the second family, and so forth. Therefore, the effectiveness of a RMS depends on the formation of the best set of product families. Therefore, a methodology for grouping products into families, which takes into account the requirements of products in RMSs, is an issue of core importance. These requirements are modularity, commonality, compatibility, reusability, and product demand. The methodology starts by calculating, for each product requirement, a matrix that summarises the similarity between pairs of products. Then, through the use of the AHP methodology, a unique matrix that comprises the similarity values between products is obtained. The Average Linkage Clustering algorithm is applied to this matrix in order to obtain a dendogram that shows the diverse sets of product families that may be formed.     

Gigabit pulse position bistability in semiconductor lasers

The paper briefly reviews the major forms of optical bistability in active optical devices compatible for use in gigabit optical communication systems, and reports an entirely new optical bistability for the first time. Unlike previous devices, the two bistable states of the optical device are each a series of picosecond optical pulses at 1 GHz or greater repetition rates, and are distinguished by a half period temporal shift between their temporal positions in relation to a clock pulse. The bistable device is based on a gain switched semiconductor laser. Theoretical studies suggest 100-ps switching speeds might be achieved, and experimental results are reported indicating optically triggered switching times of 500 ps.     

FACTORS AFFECTING THE HARDNESS OF FAT ON SIDES OF CHILLED BEEF

The influence of some factors on the hardness of subcutaneous fat on sides of chilled beef as measured by the average force resisting movement of a cutting pin (Ff) was investigated. Values of Ff determined at a fat temperature of 10°C on grass-fed animals denied water 24 h preslaughter were not significantly influenced by moisture content (5-11%) or fat depth (2-27 mm). There was a quadratic relationship (P<0.001) between the age of animals at slaughter (31-141 months) and Ff, and a linear one (P<0.001) between saturated fatty acid content (35-50%) and Ff. Values of Ffat a fat temperature of 5°C were not significantly related to moisture content (1-22%) but there was a linear relationship (P<0.01) with fat depth (5-13 mm). This had a common slope for the three feeding patterns: (1) grass-fed animals denied water 24 h preslaughter; (2) grass-fed animals given access to water 24 h preslaughter, and; (3) lot-fed animals given access to water 24 h preslaughter.